BALLOON-BORNE MEASUREMENTS OF AEROSOL VERTICAL DISTRIBUTIONS OVER BEIJING DURING THE SUMMER AND AUTUMN OF 1993

The results of two balloon soundings during the summer and autumn of 1993 from the Xianghe Observation Station are being utilized in a study of the temporal and spatial distribution of the atmospheric aerosols.The balloon,gondola,instrumentation and atmospheric conditions during the observation period are described.The temporal and spatial characteristics of aerosol concentration,size ratio,mixing ratio,and size distribution for both troposphere and strato-sphere are presented and analyzed.     

Tests for individual Sulfate－Containing Particles in Urban Atmosphere in Beijing

Thin film methods and X ray energy dispersive technique were applied to analyze sulfate-containing particles in Beijing in order to examine their features and sources. Atmospheric aerosol particles were collected on electron mi-croscope meshes according to two size ranges: coarse particles (r>0.5μm) and fine particles (0.5μm≥r≥0.1μm) by using a two-stage impactor. It was found fiat more than seventy percent of the fine particles and about twenty percent of the coarse particles were sulfate-containing particles. These particles were formed mainly through heterogeneous nucleation. The element composition analyses revealed that the atmospheric aerosol particles in Beijing were domi-nated by crustal particles and construction dust.     

对流层平流层气溶胶粒子的形态和化学组成

分析研究了１９９３年和１９９４年的８月、９月在香河地区上空采集的单个气溶胶粒子的形态及化学元素和化合物的组成。结果表明：１９９３年,在对流层大气中的气溶胶颗粒经常出现不规则形的粒子,可能是土壤粒子;而在平流层大气中的颗粒以具有“卫星”结构的硫酸粒子为主;硫酸铵粒子则经常出现在对流层的中、下部。香河地区上空颗粒物的化学元素组成比较复杂,单一化学元素组成的粒子较少,粒子主要含有Ｓｉ,Ｆｅ,Ａｌ和Ｓ等元素。气溶胶的化合物有硫酸盐、硅酸盐、硝酸盐和磷酸盐等     

Mixed layer depth climatology of the North Pacific based on Argo observations

A monthly mean climatology of the mixed layer depth (MLD) in the North Pacific has been produced by using Argo observations. The optimum method and parameter for evaluating the MLD from the Argo data are statistically determined. The MLD and its properties from each density profile were calculated with the method and parameter. The monthly mean climatology of the MLD is computed on a 2° × 2° grid with more than 30 profiles for each grid. Two bands of deep mixed layer with more than 200 m depth are found to the north and south of the Kuroshio Extension in the winter climatology, which cannot be reproduced in some previous climatologies. Early shoaling of the winter mixed layer between 20–30°N, which has been pointed out by previous studies, is also well recognized. A notable feature suggested by our climatology is that the deepest mixed layer tends to occur about one month before the mixed layer density peaks in the middle latitudes, especially in the western region, while they tend to coincide with each other in higher latitudes.     

Observational Study on the Downward Solar Radiation at the Sea Surface in the Western Pacific

In situ observation of downward solar radiation in the Western Pacific were carried out with voluntary merchant ships for five years from autumn 1990 through autumn 1995. Daily means of the short wave radiation were computed from the observed solar radiation. Then, the effects of shadows of the ship's superstructures on the observed radiation were corrected if needed. A 5-year average of short wave radiation along the main sea-lanes in the Western Pacific was calculated based on the observed daily mean solar radiation. Maximum values of 270–280 Wm^–2 are found around 15°–20°N in May and June, while those of 290 Wm^–2 are observed south of 18°S in November and December along the lanes. Small annual variations are found in the equatorial region. Annual mean values at the equator are about 230 Wm^–2 between New Guinea and Indonesia, and 200 Wm^–2 east of New Guinea. The 5-year average of short wave radiation was compared with the climatologies given in previous studies. We have concluded that some of results of previous studies are significantly underestimated.     

In situ measurement of incoming solar radiation by voluntary ships in the western Pacific

We have been performingin situ measurement of downward short wave radiation (solar radiation) in the western Pacific Ocean in cooperation with voluntary ships since autumn 1990 in order to obtain much more precise knowledge of downward short wave radiation at the sea's surface than before. Preliminary result of the observation from autumn 1990 through spring 1992 is shown in this paper. The comparison of observed daily mean downward short wave radiation with that estimated from observed cloudiness by using Reed (1977) formula is also presented to show the necessity ofin situ measurement in the study of the downward short wave radiation at the sea's surface.     

Dominant sea-surface temperature anomaly patterns in summer over the North Pacific ocean

We investigated the structure and persistency of the dominant sea-surface temperature (SST) anomaly pattern in summer over the North Pacific from 1960 to 2004, which has been attracting less attention than those in winter. The leading empirical orthogonal functions (EOFs) for August and September, which can be treated as the summer patterns, rather resemble each other in both spatial structure and time variations but are quite different from those of the other months. A lag correlation analysis indicates that the summer patterns do not show significant persistency in the following winter and the summer of the next year. An inappropriate definition of the summer season might obscure the characteristics of the dominant summer SST anomaly pattern in the North Pacific.     

Mathematical Derivation of Spatially-Averaged Momentum Equations for an Urban Canopy Model Using Underlying Concepts of the Immersed Boundary Method

We propose a new approach to derive spatially-averaged momentum equations for an urban canopy model that resolves buildings vertically and not horizontally. First, in order to mathematically describe the actual momentum field as a completely continuous field, the underling concepts of the immersed boundary method are employed, where we assume that (i) the entire simulation space, including that occupied by buildings, is filled with a fluid, and (ii) an external body force field exists that reduces the wind speed to zero at all positions coinciding with the space occupied by the buildings. Then, in order to obtain the required spatially-averaged momentum equations in a self-consistent manner, a spatial-averaging operation is applied to the Navier–Stokes equations that include a term representing the external force field. The applied spatial-averaging operation is equivalent to the conventional spatial filtering operation used in large-eddy simulations. To examine the significance of the subgrid-scale (SGS) stresses of the spatially-averaged momentum equations, a numerical simulation is performed for a flow around a regular array of cubical blocks with a grid resolution that is sufficient to resolve the blocks. By estimating the individual terms in the spatially-averaged momentum equations using the simulation results, we show that the SGS stresses contribute significantly to the spatially-averaged momentum budget, and therefore they should not be neglected in urban canopy modelling.     

A k - *epsiv Turbulence Closure Model For The Atmospheric Boundary Layer Including Urban Canopy

A numerical model for the computation of the wind field,air temperature and humidity in the atmospheric boundary layer (ABL) including the urbancanopy was developed for urban climate simulation. The governing equations of the modelare derived by applying ensemble and spatial averages to the Navier–Stokes equation, continuityequation and equations for heat and water vapour transfer in the air. With the spatial averagingprocedure, effects of buildings and other urban structures in the urban canopy can be accounted for byintroducing an effective volume function, defined as the ratio between the volume of air in acomputational mesh over the total volume of the mesh. The improved k - model accounts for the anisotropyof the turbulence field under density stratification. In the improved k - model, the transportof momentum and heat in the vertical direction under density stratification is evaluated based onthe assumption of a near-equilibrium shear flow where transport effects on the stresses andheat fluxes are negligible. The heating processes at surfaces of buildings and ground are alsomodelled. The comparison of the computational results obtained with the present modeland existing observational data and numerical models shows that the present model is capableof predicting the structure of turbulence in the urban canopy layer under density stratification.Numerical experiments with the new model show that the flow behaviour of the air in the urbancanopy layer is strongly affected by the existence of buildings and density stratification.     

Rapid change in nitrate and sulfate concentrations observed in early stage of precipitation and their deposition processes

The concentrations of H⁺, nitrate (NO₃ ^-), and sulfate (SO₄ ^2-) in rainwater and their temporal changes were analyzed on the basis of continuous observation from 1 July 1991 to 30 June 1992 at a suburb of Nagoya, Japan. The yearly average for pH was 4.4. In general, an increasing pH with increase in precipitation amount was observed for rain events. Relatively high pH rainwater was sometimes observed at the beginning of rainfall, even though high concentrations of NO₃ ^- and SO₄ ^2- were involved. The high pH values were considered to be caused by the neutralization process with particulate matter containing cations. The yearly averaged ratio of equivalent concentration of nitrate to sulfate (N/S) in rainwater was 0.58. In the early stage of rain, the N/S value was usually more than 1.0 due to the difference of scavenging process between NO₃ ^- and SO₄ ^2-. High values of N/S ranging from 5 to 10 were found under the atmospheric conditions of calm winds and low humidity, during which it is possible that atmospheric particles float for a long time in the air before a rain event. The adsorption of NO₃ ^- in the early stage of rainfall by particulate matter was suggested from the difference in scavenging processes of NO₃ ^- and SO₄ ^2-. A possible scavenging process, called limb cloud scavenging, is presented to explain the interaction of particles and nitrate ions at the early stage of rain. In limb cloud scavenging, the repeated migration of cloud particles or raindrops between the inside and outside of clouds increases the absorption of ions to a highly condensed level, thus increasing the N/S value of rainwater. The influence of global scale seasonal phenomena with large amounts of particulates, such as typhoons or Asian dust storms, was also studied.